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Title: 588. The kinetics and mechanism of the thermal cyclisation of hexa-1,cis-3,5-triene to cyclohexa-1,3-diene
Journal: J. Chem. Soc.
Page(s): 3080 - 3092
Year: 1964
Reference type: Journal article
Squib: 1964LEW/STE3080-3092
Reaction:
(Z)-CH2=CHCH=CHCH=CH2 → 1,3-Cyclohexadiene
Reaction order:
1
Temperature:
390 - 463
K
Pressure: 8.00E-2 - 0.11 bar
Rate expression:
7.14x1011 [±5.2x1011 s-1] e-121391 [±2428 J/mole]/RT
Bath gas:
(Z)-CH2=CHCH=CHCH=CH2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 390 | 3.94E-5 |
| 400 | 1.00E-4 |
| 425 | 8.60E-4 |
| 450 | 5.80E-3 |
| 463 | 1.44E-2 |