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Title: The thermal decomposition of tertiary butyl and tertiary amyl chlorides, gaseous homogeneous unimolecular reactions
Journal: J. Am. Chem. Soc.
Volume: 58
Page(s): 43 - 47
Year: 1936
Reference type: Journal article
Squib: 1936BRE/KIS43-47
Reaction:
tert-C4H9Cl → Isobutene + HCl
Reaction order:
1
Temperature:
543 - 645
K
Pressure: 3.60E-2 - 0.29 bar
Rate expression:
1.9x1014 [s-1] e-192064 [J/mole]/RT
Bath gas:
tert-C4H9Cl
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 543 | 6.36E-5 |
| 550 | 1.09E-4 |
| 575 | 6.78E-4 |
| 600 | 3.62E-3 |
| 625 | 1.69E-2 |
| 645 | 5.31E-2 |