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Author(s):   Failes, R.L.; Stimson, V.R.
Title:   The thermal decomposition of tertiary butyl chloride in the presence of sulphur hexafluoride
Journal:   Aust. J. Chem.
Volume:   15
Page(s):   437 - 442
Year:   1962
Reference type:   Journal article
Squib:   1962FAI/STI437-442

Reaction:   tert-C4H9ClIsobutene + HCl
Reaction order:   1
Temperature:   557 - 582 K
Pressure:  1.00E-1 - 0.47 bar
Rate expression:   5.0x1013 [s-1] e-187907 [J/mole]/RT
Bath gas:   SF6
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
557 1.20E-4
575 4.26E-4
582 6.83E-4