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Title: The thermal decomposition of tertiary butyl chloride in the presence of sulphur hexafluoride
Journal: Aust. J. Chem.
Volume: 15
Page(s): 437 - 442
Year: 1962
Reference type: Journal article
Squib: 1962FAI/STI437-442
Reaction:
tert-C4H9Cl → Isobutene + HCl
Reaction order:
1
Temperature:
557 - 582
K
Pressure: 1.00E-1 - 0.47 bar
Rate expression:
5.0x1013 [s-1] e-187907 [J/mole]/RT
Bath gas:
SF6
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 557 | 1.20E-4 |
| 575 | 4.26E-4 |
| 582 | 6.83E-4 |