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Title: Thermal decomposition of model compounds of polyvinyl chloride. I. Gaseous thermal decomposition of model compounds having secondary and tertiary chlorine
Journal: J. Polym. Sci.: Part A
Volume: 2
Page(s): 3505 - 3513
Year: 1964
Reference type: Journal article
Squib: 1964ASA/ONO3505-3513
Reaction:
tert-C4H9Cl → Isobutene + HCl
Reaction order:
1
Temperature:
504 - 553
K
Pressure: 1.33E-2 - 0.27 bar
Rate expression:
7.91x1012 [s-1] e-173772 [J/mole]/RT
Bath gas:
tert-C4H9Cl
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
IR absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 504 | 7.74E-6 |
| 525 | 4.07E-5 |
| 550 | 2.48E-4 |
| 553 | 3.05E-4 |