Kinetics Database Logo     Home
©NIST, 2022
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article



Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Tsang, W.
Title:   Comparative rate measurements with a single-pulse shock tube
Journal:   J. Chem. Phys.
Volume:   40
Page(s):   1171 - 1172
Year:   1964
Reference type:   Journal article
Squib:   1964TSA1171-1172

Reaction:   tert-C4H9ClIsobutene + HCl
Reaction order:   1
Reference reaction:   iso-C3H7BrCH3CH=CH2 + HBr
Temperature:   715 - 845 K
Pressure:  0.53 - 1.87 bar
Rate expression:   5.5x1013 [s-1] e-187076 [J/mole]/RT
Bath gas:   tert-C4H9Cl
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
715 1.19E0
725 1.83E0
750 5.15E0
775 1.35E1
800 3.36E1
825 7.87E1
845 1.50E2