Kinetics Database Logo     Home
©NIST, 2022
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article

Citation

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Tsang, W.
Title:   Thermal decomposition of some tert-butyl compounds at elevated temperatures
Journal:   J. Chem. Phys.
Volume:   40
Page(s):   1498 - 1505
Year:   1964
Reference type:   Journal article
Squib:   1964TSA1498-1505

Reaction:   tert-C4H9ClIsobutene + HCl
Reaction order:   1
Temperature:   750 - 950 K
Pressure:  0.11 - 0.47 bar
Rate expression:   7.94x1013 [s-1] e-192896 [J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
750 2.92E0
775 7.93E0
800 2.02E1
825 4.86E1
850 1.11E2
875 2.43E2
900 5.07E2
925 1.02E3
950 1.97E3