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Accessibility information
Author(s):   Rodgers, A.S.; Jerus, P.
Title:   Kinetics of the Bromine Catalyzed Elimination of HCl from 1,1,1-Trichloroethane
Journal:   Int J. Chem. Kinet.
Volume:   20
Page(s):   565 - 575
Year:   1988
Reference type:   Journal article
Squib:   1988ROD/JER565-575

Reaction:   CH3CCl3 + Br·HBr + CCl3CH2
Reaction order:   2
Temperature:   565 - 634 K
Pressure:  7.20E-2 - 0.27 bar
Rate expression:   3.32x10-10 [cm3/molecule s] e-83145 [±4166 J/mole]/RT
Uncertainty:   2.0
Bath gas:   Br2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
565 6.83E-18
575 9.30E-18
600 1.92E-17
625 3.74E-17
634 4.69E-17