Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Nakano, Y.; Kawasaki, M.; Ponomarev, D.A.; Hurley, M.D.; Wallington, T.J.
Title:   Kinetics and Mechanism of the Gas Phase Reaction of Cl Atoms and OH Radicals with Bromobenzene
Journal:   Chem. Phys. Lett.
Volume:   353
Page(s):   77 - 83
Year:   2002
Reference type:   Journal article
Squib:   2002NAK/KAW77-83

Reaction:   Bromobenzene + ·ClChlorobenzene + Br·
Reaction order:   2
Temperature:   295 K
Pressure:  2.67E-2 - 0.93 bar
Rate expression:   1.32x10-11 [±2.0x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In both real time and by end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Relative rate measurement, indepedent of pressure and buffer for N2, O2 and air

View full bibliographic record.