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Title: The kinetic isotope effect in the photochlorination of methane
Journal: Tetrahedron
Volume: 19
Page(s): 2009 - 2023
Year: 1963
Reference type: Journal article
Squib: 1963WIB/MOT2009-2023
Reaction:
CH2D2 + Cl2 → CHD2Cl + HCl
Reaction order:
2
Reference reaction:
CH2D2 + Cl2 → CH2DCl + DCl
Reference reaction order:
2
Temperature:
250 - 344
K
Rate expression:
1.1 e5438 [J/mole]/RT
Bath gas:
Cl2
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 250 | 1.50E1 |
| 275 | 1.19E1 |
| 300 | 9.73E0 |
| 325 | 8.23E0 |
| 344 | 7.36E0 |