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Author(s):   Wiberg, K.B.; Motell, E.L.
Title:   The kinetic isotope effect in the photochlorination of methane
Journal:   Tetrahedron
Volume:   19
Page(s):   2009 - 2023
Year:   1963
Reference type:   Journal article
Squib:   1963WIB/MOT2009-2023

Reaction:   CH2D2 + Cl2 → CHD2Cl + HCl
Reaction order:   2
Reference reaction:   CH2D2 + Cl2CH2DCl + DCl
Reference reaction order:   2
Temperature:   250 - 344 K
Rate expression:   1.1 e5438 [J/mole]/RT
Bath gas:   Cl2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
250 1.50E1
275 1.19E1
300 9.73E0
325 8.23E0
344 7.36E0