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Author(s):   Reisen, F.; Arey, J.
Title:   Reactions of Hydroxyl Radicals and Ozone with Acenaphthene and Acenaphthylene
Journal:   Environ. Sci. Technol.
Volume:   36
Page(s):   4302 - 4311
Year:   2002
Reference type:   Journal article
Squib:   2002REI/ARE4302-4311

Reaction:   Acenaphthene + ·OH → Products
Reaction order:   2
Reference reaction:   (E)-2-C4H8 + ·OH → Products
Reference reaction order:   2
Temperature:   296 K
Pressure:  0.99 bar
Rate expression:   8.0x10-11±4.0x10-12
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Relative rate measurement, OH from photolysis of methyl nitrite, TenaxTA collection (100 mL), GC-FID, reference compounds analyzed separately (column), product studies by API-MS, GC-MS and SMPS for particle formation, OH and ozone addition to the rings and double bond is the major primary pathway

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