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Accessibility information
Author(s):   Herron, J.T.; Huie, R.E.
Title:   Rate constants for the reactions of atomic oxygen (O 3P) with organic compounds in the gas phase
Journal:   J. Phys. Chem. Ref. Data
Volume:   2
Page(s):   467 - 518
Year:   1973
Reference type:   Journal article
Squib:   1973HER/HUI467-518

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1973HER/HUI467-518   CH2O + HCO + ·OH  300   1.49E-13              2
  1973HER/HUI467-518   CCl4 + ·CCl3 + ClO  270 - 380   3.32E-14       1.88E04   1.69E-17  2
  1973HER/HUI467-518   C2H5OH + → Other Products + ·OH  298   1.45E-13           1.45E-13  2
  1973HER/HUI467-518   iso-C3H7OH + → Other Products + ·OH  298   2.16E-13           2.16E-13  2
  1973HER/HUI467-518   Benzene + → Products  250 - 500   3.32E-11       1.66E04   4.04E-14  2
  1973HER/HUI467-518   CH4 + ·CH3 + ·OH  350 - 1000   3.49E-11       3.78E04      2
  1973HER/HUI467-518   CH3Br + ·OH + ·CH2Br  350 - 1000   4.98E-11       3.16E04      2
  1973HER/HUI467-518   C2H6 + ·C2H5 + ·OH  298 - 1000   4.15E-11       2.66E04   9.01E-16  2
  1973HER/HUI467-518   C2H4 + → Products  200 - 500   5.48E-12       4698   8.23E-13  2
  1973HER/HUI467-518   C2H2 + → Products  200 - 1000   2.32E-11       1.25E04   1.51E-13  2
  1973HER/HUI467-518   CH3Cl + ·OH + ·CH2Cl  298 - 1000   2.82E-11       3.07E04   1.18E-16  2
  1973HER/HUI467-518   C2H5Br + → Other Products + ·OH  298 - 1000   5.15E-11       2.71E04   9.13E-16  2
  1973HER/HUI467-518   C3H8 + → Other Products + ·OH  298   1.49E-14           1.49E-14  2
  1973HER/HUI467-518   CH3CCH + → Products  298   6.64E-13           6.64E-13  2
  1973HER/HUI467-518   C2H5Cl + → Other Products + ·OH  298 - 1000   7.97E-11       2.77E04   1.12E-15  2
  1973HER/HUI467-518   CH2=CHCl + → Products  307   8.63E-13              2
  1973HER/HUI467-518   CH2=CHF + → Products  307   4.32E-13              2
  1973HER/HUI467-518   CH3CHO + → Other Products + ·OH  298 - 500   2.32E-11       9478   5.07E-13  2
  1973HER/HUI467-518   Oxirane + ·OH + Oxiranyl  298   1.16E-15           1.16E-15  2
  1973HER/HUI467-518   iso-C3H7Br + ·OH + (CH3)2CBr  298 - 1000   3.82E-11       2.24E04   4.44E-15  2
  1973HER/HUI467-518   iso-C3H7Cl + ·OH + (CH3)2CCl  298 - 1000   4.32E-11       2.18E04   6.56E-15  2
  1973HER/HUI467-518   CH2=CF2 + → Products  307   3.65E-13              2
  1973HER/HUI467-518   COCl2 + ClCO + ClO  292   9.96E-15              2
  1973HER/HUI467-518   iso-C5H12 + → Other Products + ·OH  307   1.33E-13              2
  1973HER/HUI467-518   sec-C4H9Cl + → Other Products + ·OH  298 - 1000   5.98E-11       2.10E04   1.23E-14  2
  1973HER/HUI467-518   (CH3)2CHCH(CH3)2 + ·OH + (CH3)2CHC(·)(CH3)2  298 - 1000   5.15E-11       1.37E04   2.03E-13  2
  1973HER/HUI467-518   1,2-Dimethylbenzene + → Products  298   1.11E-12           1.11E-12  2
  1973HER/HUI467-518   Ethylbenzene + → Products  298   5.31E-13           5.31E-13  2
  1973HER/HUI467-518   1,4-Dimethylbenzene + → Products  298   7.47E-13           7.47E-13  2
  1973HER/HUI467-518   1-C4H10 + sec-C4H9 + ·OH  298 - 1000   7.64E-11       2.00E04   2.35E-14  2
  1973HER/HUI467-518   1-C4H10 + 1-C4H9 + ·OH  298 - 1000   4.98E-11       2.43E04   2.77E-15  2
  1973HER/HUI467-518   1-C4H8 + → Other Products + ·OH  180 - 500   1.59E-11       8231   5.74E-13  2
  1973HER/HUI467-518   1-C4H8 + → Products  180 - 500   3.82E-12       208   3.51E-12  2
  1973HER/HUI467-518   1,3-Butadiene + → Products  298 - 400   5.65E-12       -3159   2.02E-11  2
  1973HER/HUI467-518   Pentane, 2,4-dimethyl- + → Other Products + ·OH  307   1.66E-13              2
  1973HER/HUI467-518   1,3-Dimethylbenzene + → Products  298   1.28E-12           1.28E-12  2
  1973HER/HUI467-518   Toluene + → Products  298   2.32E-13           2.32E-13  2
  1973HER/HUI467-518   Chlorobenzene + → Products  298   5.15E-13           5.15E-13  2
  1973HER/HUI467-518   n-C4H9Br + → Other Products + ·OH  298 - 1000   7.31E-11       2.23E04   9.08E-15  2
  1973HER/HUI467-518   n-C5H12 + CH3CH2CH2CH(·)CH3 + ·OH  298 - 1000   1.66E-11       1.93E04   6.91E-15  2
  1973HER/HUI467-518   n-C5H12 + 1-C5H11 + ·OH  298 - 1000   4.82E-11       2.43E04   2.67E-15  2
  1973HER/HUI467-518   1-C5H10 + → Products  298   4.65E-12           4.65E-12  2
  1973HER/HUI467-518   1-C6H14 + 2-hexyl radical + ·OH  298 - 1000   1.83E-10       1.87E04   9.61E-14  2
  1973HER/HUI467-518   1-C6H14 + 1-hexyl radical + ·OH  298 - 1000   4.82E-11       2.43E04   2.67E-15  2
  1973HER/HUI467-518   Cyclohexane + Cyclohexyl + ·OH  298 - 1000   3.65E-10       1.95E04   1.37E-13  2
  1973HER/HUI467-518   Cyclohexene + → Products  298 - 400   4.65E-12       -3825   2.18E-11  2
  1973HER/HUI467-518   Pyridine + → Products  298   1.66E-13           1.66E-13  2
  1973HER/HUI467-518   n-C8H18 + → 2-C8H17 + ·OH  298 - 1000   1.54E-10       1.69E04   1.70E-13  2
  1973HER/HUI467-518   n-C8H18 + ·OH + 1-C8H17  298 - 1000   4.82E-11       2.43E04   2.67E-15  2
  1973HER/HUI467-518   CH3CH=CH2 + → Products  200 - 500   4.15E-12       316   3.65E-12  2
  1973HER/HUI467-518   (CH3)2O + ·OH + CH3OCH2·  200 - 500   9.80E-12       1.26E04   5.97E-14  2
  1973HER/HUI467-518   iso-C4H8 + → Products  298   1.99E-11           1.99E-11  2
  1973HER/HUI467-518   C2F4 + → Products  298 - 500   1.28E-12       831   9.13E-13  2
  1973HER/HUI467-518   CF3CF=CF2 + → Products  298 - 500   5.98E-13       7483   2.92E-14  2
  1973HER/HUI467-518   Cyclopentene + → Products  298 - 400   5.48E-12       -3575   2.32E-11  2
  1973HER/HUI467-518   1-C7H16 + ·OH + 1-C7H15  298 - 1000   4.82E-11       2.43E04   2.67E-15  2
  1973HER/HUI467-518   1-C7H16 + ·OH + 2-C7H15  298 - 1000   1.99E-10       1.82E04   1.28E-13  2
  1973HER/HUI467-518   Spiropentane + ·OH + Spiropentyl  298 - 1000   6.64E-11       2.40E04   4.08E-15  2
  1973HER/HUI467-518   Cyclopentane + ·OH + Cyclopentyl  298 - 1000   2.16E-10       1.84E04   1.30E-13  2
  1973HER/HUI467-518   Cycloheptane + ·OH + Cycloheptyl  298 - 1000   4.82E-10       1.85E04   2.71E-13  2
  1973HER/HUI467-518   CH3C(CF3)=CH2 + → Products  296   3.32E-13              2
  1973HER/HUI467-518   CH3CH2CF=CF2 + → Products  296   3.32E-12              2
  1973HER/HUI467-518   CH3CH=CF2 + → Products  296   1.83E-12              2
  1973HER/HUI467-518   1,3-Butadiyne + → Products  300   1.49E-12              2
  1973HER/HUI467-518   Fluorobenzene + → Products  298   4.48E-14           4.48E-14  2
  1973HER/HUI467-518   H2C=C=O + → Products  298   8.80E-13           8.80E-13  2
  1973HER/HUI467-518   neo-C5H12 + ·OH + Neopentyl  298 - 1000   9.80E-11       2.43E04   5.44E-15  2
  1973HER/HUI467-518   tert-C4H9Cl + ·OH + (CH3)2CClCH2  298 - 1000   4.32E-11       2.50E04   1.77E-15  2
  1973HER/HUI467-518   (CH3)2C=CHCH3 + → Products  298 - 400   6.48E-12       -5654   6.34E-11  2
  1973HER/HUI467-518   iso-C4H9Cl + → Other Products + ·OH  298 - 650   5.98E-11       2.10E04   1.27E-14  2
  1973HER/HUI467-518   (CH3)2CHCH2C(CH3)3 + → Other Products + ·OH  307   9.13E-14              2
  1973HER/HUI467-518   (CH3)2C=C(CH3)2 + → Products  298 - 400   5.65E-12       -6568   8.00E-11  2
  1973HER/HUI467-518   2,3,4-Trimethylpentane + → Other Products + ·OH  307   4.98E-14              2
  1973HER/HUI467-518   (Z)-2-C4H8 + → Products  250 - 500   9.80E-12       -1372   1.70E-11  2
  1973HER/HUI467-518   Pentane, 2,2-dimethyl- + → Other Products + ·OH  307   1.08E-13              2
  1973HER/HUI467-518   1-C6H12 + → Products  298   5.15E-12           5.15E-12  2
  1973HER/HUI467-518   CH2=CHBr + → Products  307   8.14E-13              2
  1973HER/HUI467-518   (CH3)3CC(CH3)3 + ·OH + (CH3)3CC(CH3)2CH2  307   1.33E-14              2
  1973HER/HUI467-518   (E)-2-C4H8 + → Products  298   2.32E-11           2.32E-11  2
  1973HER/HUI467-518   2-(Z)-C5H10 + → Products  298   1.83E-11           1.83E-11  2
  1973HER/HUI467-518   CH2FCH2CH=CH2 + → Products  296   2.49E-12              2
  1973HER/HUI467-518   CF2=CFCF=CF2 + → Products  305   4.15E-13              2
  1973HER/HUI467-518   t-C4H9CH2Cl + → Other Products + ·OH  298 - 1000   5.31E-11       2.22E04   6.83E-15  2
  1973HER/HUI467-518   CH2=CHCH2F + → Products  296   8.49E-13              2
  1973HER/HUI467-518   CH3CF=CH2 + → Products  296   1.99E-12              2
  1973HER/HUI467-518   CHDO + → Products  300   8.14E-14              2
  1973HER/HUI467-518   CHF=CHF(unspecified) + → Products  307   3.65E-13              2
  1973HER/HUI467-518   + n-C7H15Cl → Other Products + ·OH  298   1.33E-13       2.22E04   1.71E-17  2
  1973HER/HUI467-518   + CH2=CHCF3 → Products  296   4.32E-14              2

Search returned 89 records.