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Title: Thermal decomposition of nitryl chloride. I. Second-order unimolecular rate study
Journal: J. Am. Chem. Soc.
Volume: 76
Page(s): 4264 - 4269
Year: 1954
Reference type: Journal article
Squib: 1954COR/JOH4264-4269
Reaction:
ClNO2 → NO2 + ·Cl
Reaction order:
2
Temperature:
453 - 523
K
Pressure: 0.13 - 0.80 bar
Rate expression:
9.61x10-8 [±6.81x10-9 cm3/molecule s] e-114740 [±416 J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 453 | 5.66E-21 |
| 475 | 2.32E-20 |
| 500 | 9.92E-20 |
| 523 | 3.34E-19 |