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Title: Thermal decomposition of nitryl chlroide shock waves
Journal: J. Chem. Phys.
Volume: 36
Page(s): 2164 - 2169
Year: 1962
Reference type: Journal article
Squib: 1962HIR/HAR2164-2169
Reaction:
ClNO2 → NO2 + ·Cl
Reaction order:
2
Temperature:
686 - 1030
K
Rate expression:
2.13x10-9 [cm3/molecule s] (T/298 K)0.50 e-112245 [J/mole]/RT
Bath gas:
O2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 686 | 9.16E-18 |
| 700 | 1.37E-17 |
| 725 | 2.71E-17 |
| 750 | 5.14E-17 |
| 775 | 9.33E-17 |
| 800 | 1.63E-16 |
| 825 | 2.77E-16 |
| 850 | 4.54E-16 |
| 875 | 7.26E-16 |
| 900 | 1.13E-15 |
| 925 | 1.72E-15 |
| 950 | 2.56E-15 |
| 975 | 3.73E-15 |
| 1000 | 5.34E-15 |
| 1025 | 7.51E-15 |
| 1030 | 8.03E-15 |