Author(s):   Kaiser, E.W.; Wallington, T.J.
Title:   FTIR product study of the Cl-initiated oxidation of CH₃Cl: evidence for HCl elimination from the chloromethoxy radical
Journal:   J. Phys. Chem.
Volume:   98
Page(s):   5679 - 5685
Year:   1994
Reference type:   Journal article
Squib:   1994KAI/WAL5679-5685

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	k(298.00 K)	Order
1994KAI/WAL5679-5685	HCO + Cl₂ → HC(O)Cl + ·Cl	296	1.15		2
Reference reaction: HCO + O₂ → CO + HO₂				2
1994KAI/WAL5679-5685	O₂ + CH₂ClO → HC(O)Cl + HO₂	296	5.00E-18		2
Reference reaction: CH₂ClO → HCO + HCl				1

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