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Author(s):   Banks, J.T.; Scaiano, J.C.; Adam, W.; Oestrich, R.S.
Title:   Thermal and photochemical fragmentation of α,α-dialkoxybenzyl radicals: a comparison of the thermal reactions with laser induced fragmentations by using laser flash and laser-jet photolyses
Journal:   J. Am. Chem. Soc.
Volume:   115
Page(s):   2473 - 2477
Year:   1993
Reference type:   Journal article
Squib:   1993BAN/SCA2473-2477

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1993BAN/SCA2473-2477   Methyl, ethoxymethoxyphenyl- → Methylbenzoate + ·C2H5  329   213              1
  1993BAN/SCA2473-2477   Methyl, ethoxymethoxyphenyl- → Methylbenzoate + ·C2H5  329   6.50              1
  Reference reaction:  Methyl, ethoxymethoxyphenyl- → Ethyl benzoate + ·CH3 1
  1993BAN/SCA2473-2477   Methyl, methoxy(1-methylethoxy)phenyl- → Benzoic acid 1-methylethyl ester + ·CH3  329   1380              1
  1993BAN/SCA2473-2477   Methyl, methoxy(1-methylethoxy)phenyl- → Benzoic acid 1-methylethyl ester + ·CH3  329   >40.00              1
  Reference reaction:  Methyl, methoxy(1-methylethoxy)phenyl- → Methylbenzoate + iso-C3H7 1
  1993BAN/SCA2473-2477   Methyl, ethoxy(1-methylethoxy)phenyl- → Ethyl benzoate + iso-C3H7  329   1.66E04              1
  1993BAN/SCA2473-2477   Methyl, ethoxy(1-methylethoxy)phenyl- → Ethyl benzoate + iso-C3H7  329   12.00              1
  Reference reaction:  Methyl, ethoxy(1-methylethoxy)phenyl- → Benzoic acid 1-methylethyl ester + ·C2H5 1

Search returned 6 records.