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Home ©NIST, 2013 Accessibility information |
Title: On the mechanism of gaseous reactions. I. The thermal decomposition of methyl ethyl ether
Journal: J. Phys. Chem.
Volume: 47
Page(s): 1169 - 1182
Year: 1933
Reference type: Journal article
Squib: 1933URE/YOU1169-1182
Reaction:
C2H5OCH3 → CH4 + CH3CHO
Reaction order:
1
Temperature:
730 - 838
K
Pressure: 0.39 - 0.74 bar
Rate expression:
1.2x1015 [s-1] e-273546 [J/mole]/RT
Bath gas:
C2H5OCH3
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Other (direct)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 730 | 3.21E-5 |
| 750 | 1.07E-4 |
| 775 | 4.39E-4 |
| 800 | 1.66E-3 |
| 825 | 5.75E-3 |
| 838 | 1.07E-2 |