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Author(s):   Aders, W.-K.; Pangritz, D.; Wagner, H.Gg.
Title:   Untersuchungen zur reaktion von wasserstoffatomen mit methylfluoride, methylchlorid und methylbromid
Journal:   Ber. Bunsenges. Phys. Chem.
Volume:   79
Year:   1975
Reference type:   Journal article
Squib:   1975ADE/PAN90

Reaction:   CH3Cl + ·CH3 + HCl
Reaction order:   2
Temperature:   298 - 652 K
Pressure:  2.13E-3 - 2.40E-2 bar
Rate expression:   1.83x10-11 [±4.98x10-12 cm3/molecule s] e-19290 [±1347 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Electron spin resonance (ESR or EPR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 7.60E-15
300 8.00E-15
325 1.45E-14
350 2.41E-14
375 3.76E-14
400 5.53E-14
425 7.78E-14
450 1.05E-13
475 1.38E-13
500 1.76E-13
525 2.20E-13
550 2.69E-13
575 3.23E-13
600 3.82E-13
625 4.46E-13
650 5.15E-13
652 5.20E-13