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Espinosa-Garcia, J.; Rangel, C.
Thermochemistry data from kinetics results: A test of quality of the potential energy surface
React. Kinet. Catal. Lett.
225 - 231
CH3Cl + H· → ·CH3 + HCl
300 - 3000
no rate data available
Transition state theory
Rate constant is pressure independent
Rate constants were calculated using variational transition state theory with tunneling correction using a previously parameterized potential energy surface. Rate constants were calculated for a wide range of temperatures; however, no Arrhenius expression is given for the k(T) dependence. Instead, rate constants for individual temperatures are presented in a graphical format.
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