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Accessibility information
Author(s):   Brown, A.C.R.; James, D.G.L.
Title:   A kinetic study of the metathetical and addition reactions characteristic of allyl polymerization
Journal:   Can. J. Chem.
Volume:   40
Page(s):   796 - 803
Year:   1962
Reference type:   Journal article
Squib:   1962BRO/JAM796-803

Reaction:   CH2=CHCH2OH + ·C2H5 → CH3CH2CH2CH(·)CH2OH
Reaction order:   2
Reference reaction:   ·C2H5 + ·C2H51-C4H10
Temperature:   323 - 415 K
Rate expression:   1.24x10-12 [cm3/molecule s] e-36833 [J/mole]/RT
Bath gas:   (C2H5)2CO
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
323 1.37E-18
325 1.49E-18
350 3.95E-18
375 9.17E-18
400 1.92E-17
415 2.86E-17