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Author(s):   Tsang, W.
Title:   Mechanism and rate constants for the decomposition of 1-pentenyl radicals
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   8501 - 8509
Year:   2006
Reference type:   Journal article
Squib:   2006TSA8501-8509

Reaction:   CH2=CHCH2CH(·)CH3CH2=CHCH2CH=CH2 +
Reaction order:   1
Temperature:   500 - 2000 K
Rate expression:   2.15x1012 [s-1] (T/298 K)1.04 e-155000 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other
Pressure dependence:   Rate constant is high pressure limit
Comments:   The log(k/k) values at various pressures were presented in four parameters form

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
500 2.37E-4
600 1.43E-1
700 1.42E1
800 4.56E2
900 6.86E3
1000 6.07E4
1100 3.65E5
1200 1.64E6
1300 5.89E6
1400 1.77E7
1500 4.63E7
1600 1.08E8
1700 2.27E8
1800 4.44E8
1900 8.10E8
2000 1.40E9