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Accessibility information
Author(s):   Niedzielski, J.; Yano, T.; Tschuikow-Roux, E.
Title:   Primary kinetic effect in the gas phase photochlorination of ethyl chloride-1-d1
Journal:   Can. J. Chem.
Volume:   62
Page(s):   899 - 906
Year:   1984
Reference type:   Journal article
Squib:   1984NIE/YAN899-906

Reaction:   C2H5Cl + ·ClHCl + CH3CHCl
Reaction order:   2
Reference reaction:   CH3CHDCl + ·Cl → CH3CDCl· + HCl
Reference reaction order:   2
Temperature:   280 - 368 K
Pressure:  2.80E-2 bar
Rate expression:   1.98±5.9x10-2 e524 [±168 J/mole]/RT
Bath gas:   C2H5Cl
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
280 2.48E0
300 2.44E0
325 2.40E0
350 2.37E0
368 2.35E0