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Accessibility information
Author(s):   Tschuikow-Roux, E.; Yano, T.; Niedzielski, J.
Title:   Photochlorination of chloroethane and chloroethane-d5
Journal:   J. Phys. Chem.
Volume:   88
Page(s):   1408 - 1414
Year:   1984
Reference type:   Journal article
Squib:   1984TSC/YAN1408-1414

Reaction:   C2H5Cl + ·ClHCl + CH3CHCl
Reaction order:   2
Reference reaction:   C2H5Cl + ·ClHCl + CH2CH2Cl
Reference reaction order:   2
Temperature:   280 - 368 K
Pressure:  2.67E-2 bar
Rate expression:   1.06±4.3x10-2 e-3401 [J/mole]/RT
Bath gas:   C2H5Cl
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
280 2.46E-1
300 2.71E-1
325 3.01E-1
350 3.29E-1
368 3.49E-1