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Author(s):   Bryukov, M.G.; Slagle, I.R.; Knyazev, V.D.
Title:   Kinetics of Reactions of Cl Atoms with Ethane, Chloroethane, and 1,1-Dichloroethane
Journal:   J. Phys. Chem. A
Volume:   107
Page(s):   6565 - 6573
Year:   2003
Reference type:   Journal article
Squib:   2003BRY/SLA6565-6573

Reaction:   C2H5Cl + ·ClHCl + CH3CHCl
Reaction order:   2
Temperature:   296 - 810 K
Pressure:  3.07E-3 - 1.23E-2 bar
Rate expression:   2.76x10-11 [±2.8x10-12 cm3/molecule s] e-3783 [±366 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
296 5.93E-12
300 6.06E-12
350 7.52E-12
400 8.85E-12
450 1.00E-11
500 1.11E-11
550 1.21E-11
600 1.29E-11
650 1.37E-11
700 1.44E-11
750 1.50E-11
800 1.56E-11
810 1.57E-11