Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Bryukov, M.G.; Slagle, I.R.; Knyazev, V.D.
Title:   Kinetics of Reactions of Cl Atoms with Ethane, Chloroethane, and 1,1-Dichloroethane
Journal:   J. Phys. Chem. A
Volume:   107
Page(s):   6565 - 6573
Year:   2003
Reference type:   Journal article
Squib:   2003BRY/SLA6565-6573

Reaction:   C2H5Cl + ·ClHCl + CH3CHCl
Reaction order:   2
Temperature:   296 - 810 K
Pressure:  3.07E-3 - 1.23E-2 bar
Rate expression:   2.76x10-11 [±2.8x10-12 cm3/molecule s] e-3783 [±366 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Resonance fluorescence

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
296 5.93E-12
300 6.06E-12
350 7.52E-12
400 8.85E-12
450 1.00E-11
500 1.11E-11
550 1.21E-11
600 1.29E-11
650 1.37E-11
700 1.44E-11
750 1.50E-11
800 1.56E-11
810 1.57E-11