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Author(s):   Sarzynski, D.; Gola, A.A.; Brudnik, K.; Berkowski, R.; Jodkowski, J.T.
Title:   Temperature dependence of the kinetic isotopic effect of the reaction of Cl atoms with C2H5Cl between 298 and 550 K
Journal:   Chem. Phys. Lett.
Volume:   554
Page(s):   20 - 26
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012SAR/GOL20-26

Reaction:   C2H5Cl + ·ClHCl + CH3CHCl
Reaction order:   2
Reference reaction:   CH3Cl + ·Cl·CH2Cl + HCl
Temperature:   298 - 550 K
Pressure:  0.13 - 1.00 bar
Rate expression:   1.36x10-11 [±9.0x10-13 cm3/molecule s] e-1680 [±66.52 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   The error limits represent 2σ statistical uncertainties.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 6.90E-12
300 6.94E-12
325 7.30E-12
350 7.64E-12
375 7.94E-12
400 8.21E-12
425 8.46E-12
450 8.68E-12
475 8.89E-12
500 9.08E-12
525 9.26E-12
550 9.42E-12