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Title: Rate constants for the reactions of fluorine atoms with alkanes and hydrofluorocarbons at room temperature
Journal: J. Chem. Soc. Faraday Trans.
Volume: 91
Page(s): 3041 - 3044
Year: 1995
Reference type: Journal article
Squib: 1995MOO/SMI3041-3044
Reaction:
CH2F2 + ·F → ·CHF2 + HF
Reaction order:
2
Reference reaction:
HCl + ·F → HF + ·Cl
Reference reaction order:
2
Temperature:
298
K
Pressure: 0.80 bar
Rate expression:
6.7x10-1±1.2x10-1
Bath gas:
N2
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Fourier transform (FTIR)
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