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Author(s):   Liu, D.; Giri, B.R.; Farooq, A.
Title:   Cyclic Ketones as Future Fuels: Reactivity with OH Radicals
Journal:   J. Phys. Chem. A
Volume:   123
Page(s):   4325 - 4332
Year:   2019
Reference type:   Journal article
Squib:   2019LIU/GIR4325-4332

Reaction:   Cyclopentanone + ·OH → Products
Reaction order:   2
Temperature:   902 - 1297 K
Pressure:  1.13 - 1.64 bar
Rate expression:   1.2x10-10 [cm3/molecule s] e-17585 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   The rate coefficients have an overall uncertainty (2σ) of ±20%.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
902 1.15E-11
925 1.22E-11
950 1.30E-11
975 1.37E-11
1000 1.45E-11
1025 1.52E-11
1050 1.60E-11
1075 1.68E-11
1100 1.75E-11
1125 1.83E-11
1150 1.91E-11
1175 1.98E-11
1200 2.06E-11
1225 2.13E-11
1250 2.21E-11
1275 2.28E-11
1297 2.35E-11