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Author(s):   Liu, D.; Giri, B.R.; Farooq, A.
Title:   Cyclic Ketones as Future Fuels: Reactivity with OH Radicals
Journal:   J. Phys. Chem. A
Volume:   123
Page(s):   4325 - 4332
Year:   2019
Reference type:   Journal article
Squib:   2019LIU/GIR4325-4332

Reaction:   Cyclopentanone + ·OH → Products
Reaction order:   2
Temperature:   298 - 1297 K
Rate expression:   1.05x10-13 [cm3/molecule s] (T/298 K)3.20 e8362 [J/mole]/RT
Category:  Experiment
Data type:   Experimental value and limited review
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Combination of the experimental data from the current study and a room temperature value from the literature.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 3.06E-12
300 3.06E-12
350 3.10E-12
400 3.32E-12
450 3.66E-12
500 4.10E-12
550 4.63E-12
600 5.26E-12
650 5.97E-12
700 6.77E-12
750 7.68E-12
800 8.68E-12
850 9.79E-12
900 1.10E-11
950 1.23E-11
1000 1.38E-11
1050 1.54E-11
1100 1.71E-11
1150 1.89E-11
1200 2.09E-11
1250 2.30E-11
1297 2.52E-11