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Author(s):   Sway, M.
Title:   Kinetics of abstraction reactions of methyl radicals with alkanes in gas phase
Journal:   Indian J. Chem.
Volume:   29
Year:   1990
Reference type:   Journal article
Squib:   1990SWA748

Reaction:   iso-C4H10 + ·CH3CH4 + tert-C4H9
Reaction order:   2
Reference reaction:   ·CH3 + ·CH3C2H6
Temperature:   399 - 434 K
Pressure:  0.67 bar
Rate expression:   3.02x10-13 [cm3/molecule s] e-34172 [±2395 J/mole]/RT
Uncertainty:   1.60000002
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
399 1.02E-17
400 1.04E-17
425 1.91E-17
434 2.33E-17