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Author(s):   Zhang, H.X.; Back, M.H.
Title:   Comment: A re-evaluation of the rate constant for abstraction of hydrogen from isobutane by methyl radicals
Journal:   Int. J. Chem. Kinet.
Volume:   22
Year:   1990
Reference type:   Journal article
Squib:   1990ZHA/BAC537

Reaction:   iso-C4H10 + ·CH3CH4 + tert-C4H9
Reaction order:   2
Reference reaction:   iso-C4H10 + ·CH3CH4 + iso-C4H9
Reference reaction order:   2
Temperature:   500 - 855 K
Rate expression:   1.82x10-1 e14633 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
500 6.15E0
525 5.20E0
550 4.46E0
575 3.88E0
600 3.42E0
625 3.04E0
650 2.73E0
675 2.47E0
700 2.25E0
725 2.06E0
750 1.90E0
775 1.76E0
800 1.64E0
825 1.54E0
850 1.44E0
855 1.43E0