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Accessibility information
Author(s):   Batt, L.; McCulloch, R.D.; Milne, R.T.
Title:   Thermochemical and Kinetic Studies of Alkyl Nitrites (RONO)-D(RO-NO), The Reactions between RO. and NO, and the Decomposition RO.
Journal:   Proc. Symp. Chem. Kinet. Data Upper Lower Atmos. 1974
Page(s):  
Year:   1975
Reference type:   Journal article
Squib:   1975BAT/MCC441

Reaction:   i-C3H7ONO → Acetone + HNO
Reaction order:   1
Temperature:   393 - 473 K
Pressure:  0.91 bar
Rate expression:   1.26x109 [s-1] e-111414 [J/mole]/RT
Uncertainty:   3.16000009
Bath gas:   CF4
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
393 1.96E-6
400 3.56E-6
425 2.55E-5
450 1.47E-4
473 6.26E-4