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Title: The Gas-Phase Pyrolysis of Alkyl Nitrites. VII. Primary and Secondary Nitrites in the Presence of Nitric Oxide
Journal: Int. J. Chem. Kinet.
Volume: 10
Page(s):
Year: 1978
Reference type: Journal article
Squib: 1978BAT/ISL1195
Reaction:
i-C3H7ONO → Acetone + HNO
Reaction order:
1
Temperature:
433 - 473
K
Pressure: 1.01 bar
Rate expression:
2.0x1014 [s-1] e-162964 [±4881 J/mole]/RT
Uncertainty:
3.16000009
Bath gas:
NO
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 433 | 4.39E-6 |
| 450 | 2.43E-5 |
| 473 | 2.02E-4 |