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Accessibility information
Author(s):   Roth, W.R.; Hunold, F.
Title:   Bildungsenthalpie und Stabilisierungsenergie des Pentamethylcyclopentadienyl-Radikals
Journal:   Liebigs Ann.
Page(s):   1119 - 1122
Year:   1995
Reference type:   Journal article
Squib:   1995ROT/HUN1119-1122

Reaction:   Bi-2,4-Cyclopentadien-1-yl, 1,1',2,2',3,3',4,4',5,5'-decamethyl- → 1,3-Cyclopentadiene, pentamethyl- + 1,3-Cyclopentadiene, 1,2,3,4-tetramethyl-5-methylene-
Reaction order:   1
Temperature:   343 - 383 K
Pressure:  1.33E-3 - 8.00E-2 bar
Rate expression:   3.39x1013 [s-1] e-123054 [±1231 J/mole]/RT
Uncertainty:   1.40999997
Bath gas:   O2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
343 6.18E-6
350 1.46E-5
375 2.45E-4
383 5.60E-4