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Accessibility information
Author(s):   Melius, C.F.; Miller, J.A.; Evleth, E.M.
Title:   Unimolecular reaction mechanisms involving C3H4, C4H4, and C6H6 hydrocarbon species
Journal:   Symp. Int. Combust. Proc.
Volume:   24
Page(s):   621 - 628
Year:   1992
Reference type:   Journal article
Squib:   1992MEL/MIL621-628

Reaction:   CD≡CCH2CH2CH2C≡CD → CH2=C=CCDCD=C=CH2
Reaction order:   1
Temperature:   523 - 673 K
Rate expression:   1.91x1012 [s-1] e-118066 [J/mole]/RT
Category:  Theory
Data type:   Other theoretical

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
523 3.09E0
525 3.42E0
550 1.17E1
575 3.60E1
600 1.01E2
625 2.59E2
650 6.21E2
673 1.31E3