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Author(s):   Lifshitz, A.; Tamburu, C.; Dubnikova, F.
Title:   Reactions of 1-Naphthyl Radicals with Acetylene. Single-Pulse Shock Tube Experiments and Quantum Chemical Calculations. Differences and Similarities in the Reaction with Ethylene
Journal:   J. Phys. Chem. A
Volume:   113
Page(s):   10446 - 10451
Year:   2009
Reference type:   Journal article
Squib:   2009LIF/TAM10446-10451

Reaction:   1-naphthyl-2-vinyl → C2H2 + 1-Naphthalenyl
Reaction order:   1
Temperature:   1050 K
Rate expression:   1.24x107 [s-1]
Category:  Theory
Data type:   Derived from detailed balance/reverse rate
Pressure dependence:   Rate constant is high pressure limit
Comments:   Reaction barrier for the reverse reaction was calculated using quantum chemistry but the preexponential factor was estimated based on analogy with similar reactions.

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