NIST Chemical Kinetics Database

Author(s):   Tsang, W.
Title:   The stability of alkyl radicals
Journal:   J. Am. Chem. Soc.
Volume:   107
Page(s):   2872 - 2880
Year:   1985
Reference type:   Journal article
Squib:   1985TSA2872-2880

Reaction:   sec-C₄H₉ → (E)-2-C₄H₈ + H·
Reaction order:   1
Temperature:   300 - 800 K
Rate expression:   4.57x10¹² [s^-1] e^{-142177 [J/mole]/RT}
Category: Experiment
Data type:   Derived from detailed balance/reverse rate

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Rate constant values calculated from the Arrhenius expression:

T (K)	k(T) [s^-1]
300	8.04E-13
350	2.76E-9
400	1.24E-6
450	1.43E-4
500	6.41E-3
550	1.44E-1
600	1.92E0
650	1.72E1
700	1.12E2
750	5.73E2
800	2.38E3