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Accessibility information
Author(s):   Orlando, J.J.
Title:   The atmospheric oxidation of diethyl ether: chemistry of the C2H5-O-CH(O·)CH3 radical between 218 and 335 K
Journal:   Phys. Chem. Chem. Phys.
Volume:   9
Page(s):   4189 - 4199
Year:   2007
Reference type:   Journal article
Squib:   2007ORL4189-4199

Reaction:   C2H5OCHO·CH3HC(O)OC2H5 + ·CH3
Reaction order:   1
Reference reaction:   C2H5OCHO·CH3 + O2CH3C(O)OC2H5 + HO2
Reference reaction order:   2
Temperature:   218 - 335 K
Pressure:  6.67E-2 - 0.93 bar
Rate expression:   6.9x1024 [molecule/cm3] e-26024 [J/mole]/RT
Category:  Experiment
Data type:   Relative rate value measured
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In both real time and by end product analysis
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [molecule/cm3]
218 4.01E18
225 6.27E18
250 2.52E19
275 7.87E19
300 2.03E20
325 4.53E20
335 6.04E20