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Accessibility information
Author(s):   Croce, A.E.; Castellano, E.
Title:   Kinetics and mechanism of the gas-phase thermal reaction between bis(fluoroxy) difluoromethane CF2(OF)2 and carbon monoxide
Journal:   Int. J. Chem. Kinet.
Volume:   14
Page(s):   647 - 657
Year:   1982
Reference type:   Journal article
Squib:   1982CRO/CAS647-657

Reaction:   CO + (FO)2=CF2 → FCO + CF3O2
Reaction order:   2
Temperature:   383 - 413 K
Pressure:  6.00E-2 - 0.33 bar
Rate expression:   6.03x10-12 [cm3/molecule s] e-87302 [J/mole]/RT
Bath gas:   CO
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
383 7.48E-24
400 2.40E-23
413 5.48E-23