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Author(s):   Bilde, M.; Mogelberg, T.E.; Sehested, J.; Nielsen, O.J.; Wallington, T.J.; Hurley, M.D.; Japar, S.M.; Dill, M.; Orkin, V.L.; Buckley, T.J.; Huie, R.E.; Kurylo, M.J.
Title:   Atmospheric chemistry of dimethyl carbonate: reaction with OH radicals, UV spectra of CH3OC(O)OCH2 and CH3OC(O)OCH2O2 radicals, reactions of CH3OC(O)OCH2O2 with NO and NO2, and fate of CH3OC(O)OCH2O radicals
Journal:   J. Phys. Chem. A
Volume:   101
Page(s):   3514 - 3525
Year:   1997
Reference type:   Journal article
Squib:   1997BIL/MOG3514-3525

Reaction:   ·Cl + CH3OC(O)OCH2Cl → Products
Reaction order:   2
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   4.6x10-13 [±2.82x10-13 cm3/molecule s]
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)

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