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Title: Rate constant for the reaction of CH3C(O)CH2 radical with HBr and its thermochemical implication
Journal: Int. J. Chem. Kinet.
Volume: 38
Page(s): 32 - 37
Year: 2006
Reference type: Journal article
Squib: 2006FAR/KOV32-37
Reaction:
CH3C(O)CH2(·) + HBr → Acetone + Br·
Reaction order:
2
Temperature:
298
K
Pressure: 3.55E-3 bar
Rate expression:
3.04x10-14 [±1.99x10-15 cm3/molecule s]
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Flow tube - Data taken vs distance
Excitation technique:
Discharge
Time resolution:
By end product analysis
Analytical technique:
Laser induced fluorescence
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