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Author(s):   Yoshizawa, H.; Nagashima, H.; Murakami, Y.; Takahashi, K.
Title:   Kinetic Studies on the Reactions of Atomic Oxygen with Furan, 2-Methylfuran, and 2,5-Dimethylfuran at Elevated Temperatures
Journal:   Chem. Lett.
Volume:   46
Page(s):   1207 - 1210
Year:   2017
Reference type:   Journal article
Squib:   2017YOS/NAG1207-1210

Reaction:   2-Methylfuran + → Products
Reaction order:   2
Temperature:   898 - 1412 K
Pressure:  4.73E-2 - 6.33E-2 bar
Rate expression:   2.09x10-9 [cm3/molecule s] e-32100 [±3400 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Error limits are expressed as two standard deviations. The uncertainty in the preexponential factor is expressed as follows: A = 10-8.68 ± 0.16 cm3 molecule-1 s-1.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
898 2.84E-11
900 2.87E-11
950 3.59E-11
1000 4.40E-11
1050 5.29E-11
1100 6.25E-11
1150 7.28E-11
1200 8.37E-11
1250 9.52E-11
1300 1.07E-10
1350 1.20E-10
1400 1.33E-10
1412 1.36E-10