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Title: Kinetic Studies on the Reactions of Atomic Oxygen with Furan, 2-Methylfuran, and 2,5-Dimethylfuran at Elevated Temperatures
Journal: Chem. Lett.
Volume: 46
Page(s): 1207 - 1210
Year: 2017
Reference type: Journal article
Squib: 2017YOS/NAG1207-1210
Reaction:
2-Methylfuran + O· → Products
Reaction order:
2
Temperature:
898 - 1412
K
Pressure: 4.73E-2 - 6.33E-2 bar
Rate expression:
2.09x10-9 [cm3/molecule s] e-32100 [±3400 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Shock tube
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
Comments:
Error limits are expressed as two standard deviations. The uncertainty in the preexponential factor is expressed as follows: A = 10-8.68 ± 0.16 cm3 molecule-1 s-1.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 898 | 2.84E-11 |
| 900 | 2.87E-11 |
| 950 | 3.59E-11 |
| 1000 | 4.40E-11 |
| 1050 | 5.29E-11 |
| 1100 | 6.25E-11 |
| 1150 | 7.28E-11 |
| 1200 | 8.37E-11 |
| 1250 | 9.52E-11 |
| 1300 | 1.07E-10 |
| 1350 | 1.20E-10 |
| 1400 | 1.33E-10 |
| 1412 | 1.36E-10 |