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Title: Reaction of oxygen atoms with nitromethane and with nitroethane
Journal: J. Chem. Soc. Faraday Trans. 1
Volume: 73
Page(s):
Year: 1977
Reference type: Journal article
Squib: 1977SAL/THR2025
Reaction:
C2H5NO2 + O· → Products
Reaction order:
2
Temperature:
294 - 473
K
Pressure: 2.00E-3 - 1.00E-2 bar
Rate expression:
5.25x10-11 [cm3/molecule s] e-22699 [±7034 J/mole]/RT
Uncertainty:
5.0
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Electron beam
Analytical technique:
Vis-UV emission
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 294 | 4.87E-15 |
| 300 | 5.86E-15 |
| 325 | 1.18E-14 |
| 350 | 2.15E-14 |
| 375 | 3.62E-14 |
| 400 | 5.70E-14 |
| 425 | 8.52E-14 |
| 450 | 1.22E-13 |
| 473 | 1.63E-13 |