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Author(s):   Szilagyi, I.; Berces, T.
Title:   Thermal decomposition of benzotrifluoride. The C-C bond strength and the heat of formation of the phenyl radical
Journal:   Int. J. Chem. Kinet.
Volume:   2
Page(s):   199 - 213
Year:   1970
Reference type:   Journal article
Squib:   1970SZI/BER199-213

Reaction:   Trifluoromethylbenzene·CF3 + Phenyl
Reaction order:   1
Temperature:   993 - 1130 K
Pressure:  2.40E-2 - 8.53E-2 bar
Rate expression:   7.94x1017 [s-1] e-417386 [±12555 J/mole]/RT
Uncertainty:   3.16000009
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
993 8.80E-5
1000 1.25E-4
1025 4.27E-4
1050 1.37E-3
1075 4.16E-3
1100 1.20E-2
1125 3.32E-2
1130 4.04E-2