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Accessibility information
Author(s):   Quick, L.M.; Whittle, E.
Title:   Reactions of trifluoromethyl radicals with organic halides. Part 7.-Chloro- and fluorochloro-ethanes
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   68
Year:   1972
Reference type:   Journal article
Squib:   1972QUI/WHI878

Reaction:   CH3CCl3 + ·CF3CF3Cl + CH3CCl2·
Reaction order:   2
Reference reaction:   ·CF3 + ·CF3C2F6
Temperature:   339 - 478 K
Pressure:  4.80E-2 - 7.07E-2 bar
Rate expression:   5.25x10-13 [cm3/molecule s] e-40575 [±2436 J/mole]/RT
Uncertainty:   2.0
Bath gas:   (CF3)2CO
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
339 2.94E-19
350 4.62E-19
375 1.17E-18
400 2.64E-18
425 5.41E-18
450 1.02E-17
475 1.81E-17
478 1.93E-17