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Accessibility information
Author(s):   Brand, U.; Hippler, H.; Lindemann, L.; Troe, J.
Title:   C-C and C-H bond splits of laser-excited aromatic molecules. 1. Specific and thermally averaged rate constants
Journal:   J. Phys. Chem.
Volume:   94
Page(s):   6305 - 6316
Year:   1990
Reference type:   Journal article
Squib:   1990BRA/HIP6305-6316

Reaction:   4-Methylbenzyl + 1,4-Dimethylbenzene
Reaction order:   2
Temperature:   300 - 1900 K
Rate expression:   4.15x10-10 [cm3/molecule s] e-698 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 3.14E-10
400 3.37E-10
500 3.51E-10
600 3.61E-10
700 3.68E-10
800 3.74E-10
900 3.78E-10
1000 3.82E-10
1100 3.85E-10
1200 3.87E-10
1300 3.89E-10
1400 3.91E-10
1500 3.93E-10
1600 3.94E-10
1700 3.95E-10
1800 3.96E-10
1900 3.97E-10