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Title: Abstraction reaction of the allyl radical with toluene
Journal: J. Chem. Soc. Chem. Commun.
Volume: 13
Page(s):
Year: 1966
Reference type: Journal article
Squib: 1966AKE/THR432
Reaction:
Toluene + ·CH2CH=CH2 → CH3CH=CH2 + Benzyl
Reaction order:
2
Reference reaction:
·CH2CH=CH2 + ·CH3 → 1-C4H8
Reference reaction order:
2
Temperature:
850 - 950
K
Rate expression:
2.8x10-1 e-46894 [J/mole]/RT
Bath gas:
Toluene
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Thermal
Analytical technique:
Other (direct)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 850 | 3.68E-4 |
| 875 | 4.44E-4 |
| 900 | 5.32E-4 |
| 925 | 6.30E-4 |
| 950 | 7.39E-4 |