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Accessibility information
Author(s):   Heydtmann, H.; Rinck, G.
Title:   Die Kinetik des thermischen Zerfalls von 2-Chlorbutan in der Gasphase
Journal:   Z. Phys. Chem. (Neue Folge)
Volume:   30
Page(s):   250 - 261
Year:   1961
Reference type:   Journal article
Squib:   1961HEY/RIN250-261

Reaction:   sec-C4H9Cl → Other Products + HCl
Reaction order:   1
Temperature:   589 - 666 K
Pressure:  6.67E-3 - 0.59 bar
Rate expression:   1.0x1014 [s-1] e-212019 [±2120 J/mole]/RT
Uncertainty:   1.77999997
Bath gas:   sec-C4H9Cl
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
589 1.58E-5
600 3.49E-5
625 1.91E-4
650 9.17E-4
666 2.35E-3