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Accessibility information
Author(s):   Maccoll, A.; Stone, R.H.
Title:   Gas-phase eliminations. Part II. The pyrolysis of s-butyl chloride, and the direction of eliminations from s-butyl compounds
Journal:   J. Chem. Soc. London
Page(s):   2756 - 2761
Year:   1961
Reference type:   Journal article
Squib:   1961MAC/STO2756-2761

Reaction:   sec-C4H9Cl → Other Products + HCl
Reaction order:   1
Temperature:   603 - 663 K
Pressure:  0.18 - 0.65 bar
Rate expression:   4.14x1013 [s-1] e-207862 [J/mole]/RT
Bath gas:   sec-C4H9Cl
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
603 4.09E-5
625 1.76E-4
650 8.19E-4
663 1.74E-3