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Accessibility information
Author(s):   Heydtmann, H.; Rinck, G.
Title:   Die Kinetik des thermischen Zerfalls von 2-Chlorbutan in der Gasphase, II
Journal:   Z. Phys. Chem. (Neue Folge)
Volume:   36
Page(s):   75 - 81
Year:   1963
Reference type:   Journal article
Squib:   1963HEY/RIN75-81

Reaction:   sec-C4H9Cl → Other Products + HCl
Reaction order:   1
Temperature:   556 - 696 K
Pressure:  9.87E-2 - 0.30 bar
Rate expression:   1.17x1014 [s-1] e-212019 [±2120 J/mole]/RT
Uncertainty:   1.39999998
Bath gas:   sec-C4H9Cl
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
556 1.41E-6
575 6.43E-6
600 4.08E-5
625 2.23E-4
650 1.07E-3
675 4.59E-3
696 1.43E-2