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Author(s):   Beach, S.D.; Hickson, K.M.; Smith, I.W.M.; Tuckett, R.P.
Title:   Rate Constants and Arrhenius Parameters for the Reactions of OH Radicals and Cl Atoms with CF3CH2OCHF2, CF3CHClOCHF2 and CF3CH2OCClF2, Using the Discharge-Flow/Resonance Fluorescence Method
Journal:   Phys. Chem. Chem. Phys.
Volume:   3
Page(s):   3064 - 3069
Year:   2001
Reference type:   Journal article
Squib:   2001BEA/HIC3064-3069

Reaction:   ·Cl + CHF2OCHClCF3 → Products
Reaction order:   2
Temperature:   318 - 399 K
Pressure:  2.67E-3 - 4.53E-3 bar
Rate expression:   7.8x10-11 [±2.6x10-11 cm3/molecule s] e-24777 [±1081 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   In real time
Analytical technique:   Resonance fluorescence
Comments:   Reported uncertainties are two sigma and are precision only.

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
318 6.64E-15
325 8.13E-15
350 1.56E-14
375 2.76E-14
399 4.45E-14