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Author(s):   Hickson, K.M.; Smith, I.W.M.
Title:   Rate Constants and Arrhenius Parameters for the Reactions of Cl Atoms with the Halogenated Ethers: CF3CH2OCHF2, CF3CHClOCHF2, and CF3CH2OCClF2
Journal:   Int. J. Chem. Kinet.
Volume:   33
Page(s):   165 - 172
Year:   2001
Reference type:   Journal article
Squib:   2001HIC/SMI165-172

Reaction:   ·Cl + CHF2OCHClCF3 → Products
Reaction order:   2
Reference reaction:   CD4 + ·ClCD3 + DCl
Temperature:   295 - 363 K
Pressure:  0.93 bar
Rate expression:   1.6x10-11 [±2.0x10-12 cm3/molecule s] e-20370 [±2079 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In both real time and by end product analysis
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
295 3.96E-15
300 4.54E-15
325 8.52E-15
350 1.46E-14
363 1.87E-14